化学
电位滴定法
钠
临界胶束浓度
吉布斯自由能
威猛牌
相图
克拉夫特温度
表面张力
动态光散射
分析化学(期刊)
相(物质)
色谱法
胶束
无机化学
热力学
物理化学
化学工程
有机化学
吸附
水溶液
离子
物理
工程类
纳米颗粒
作者
Qianjie Zhang,Chenghao He,Dongmei Zhang,Wen Jiang,Huiwen Zhang,Wanping Zhang
出处
期刊:Tenside Surfactants Detergents
[De Gruyter]
日期:2022-07-14
卷期号:59 (5): 409-423
被引量:1
标识
DOI:10.1515/tsd-2021-2399
摘要
Abstract The physical and chemical properties of sodium lauryl glutamate were systematically investigated in this work. To determine the critical micelle concentration (CMC) of sodium lauryl glutamate, the surface tension was measured using the Wilhelmy plate method. The Krafft point was determined using the ultraviolet/visible spectrophotometer. The effect of pH on the solute in the solution was studied using potentiometric titration. The critical packing parameter (CPP) and Gibbs free energy (ΔG) of micelle formation were calculated using the corresponding parameters. The temperature-concentration phase diagram of sodium lauryl glutamate was constructed using the dynamic light scattering system (DLS) and polarised optical microscopy (POM). The calculated theoretical data were combined with the actual observed data from the phase diagram. Finally, the phase behaviour of sodium lauryl glutamate was determined.
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