Microporous Carbon Nanoplates from Regenerated Silk Proteins for Supercapacitors

Advanced MaterialsVolume 25, Issue 14 p. 1993-1998 Communication Microporous Carbon Nanoplates from Regenerated Silk Proteins for Supercapacitors Young Soo Yun, Young Soo Yun Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea, Fax: (+82) 32-865-5178Search for more papers by this authorSe Youn Cho, Se Youn Cho Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea, Fax: (+82) 32-865-5178Search for more papers by this authorJinyong Shim, Jinyong Shim Department of Chemical Engineering, Inha University, Incheon 402-751, South KoreaSearch for more papers by this authorByung Hoon Kim, Byung Hoon Kim Department of Physics, University of Incheon, Incheon 406-772, Republic of KoreaSearch for more papers by this authorSung-Jin Chang, Sung-Jin Chang Division of Materials Science, Korea Basic Science Institute (KBSI), Daejeon 305-333, South KoreaSearch for more papers by this authorSeung Jae Baek, Seung Jae Baek Department of Physics and Astronomy and Department of Nano Science and Technology, Seoul National University, Seoul 151-747, South KoreaSearch for more papers by this authorYun Suk Huh, Yun Suk Huh Department of Biological Engineering, Inha University, Incheon 402-751, South KoreaSearch for more papers by this authorYongsug Tak, Yongsug Tak Department of Chemical Engineering, Inha University, Incheon 402-751, South KoreaSearch for more papers by this authorYung Woo Park, Yung Woo Park Department of Physics and Astronomy and Department of Nano Science and Technology, Seoul National University, Seoul 151-747, South KoreaSearch for more papers by this authorSungjin Park, Sungjin Park Department of Chemistry, Inha University, Incheon 402-751, South KoreaSearch for more papers by this authorHyoung-Joon Jin, Corresponding Author Hyoung-Joon Jin [email protected] Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea, Fax: (+82) 32-865-5178Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea, Fax: (+82) 32-865-5178.Search for more papers by this author Young Soo Yun, Young Soo Yun Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea, Fax: (+82) 32-865-5178Search for more papers by this authorSe Youn Cho, Se Youn Cho Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea, Fax: (+82) 32-865-5178Search for more papers by this authorJinyong Shim, Jinyong Shim Department of Chemical Engineering, Inha University, Incheon 402-751, South KoreaSearch for more papers by this authorByung Hoon Kim, Byung Hoon Kim Department of Physics, University of Incheon, Incheon 406-772, Republic of KoreaSearch for more papers by this authorSung-Jin Chang, Sung-Jin Chang Division of Materials Science, Korea Basic Science Institute (KBSI), Daejeon 305-333, South KoreaSearch for more papers by this authorSeung Jae Baek, Seung Jae Baek Department of Physics and Astronomy and Department of Nano Science and Technology, Seoul National University, Seoul 151-747, South KoreaSearch for more papers by this authorYun Suk Huh, Yun Suk Huh Department of Biological Engineering, Inha University, Incheon 402-751, South KoreaSearch for more papers by this authorYongsug Tak, Yongsug Tak Department of Chemical Engineering, Inha University, Incheon 402-751, South KoreaSearch for more papers by this authorYung Woo Park, Yung Woo Park Department of Physics and Astronomy and Department of Nano Science and Technology, Seoul National University, Seoul 151-747, South KoreaSearch for more papers by this authorSungjin Park, Sungjin Park Department of Chemistry, Inha University, Incheon 402-751, South KoreaSearch for more papers by this authorHyoung-Joon Jin, Corresponding Author Hyoung-Joon Jin [email protected] Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea, Fax: (+82) 32-865-5178Department of Polymer Science and Engineering, Inha University, Incheon 402-751, South Korea, Fax: (+82) 32-865-5178.Search for more papers by this author First published: 25 February 2013 https://doi.org/10.1002/adma.201204692Citations: 465Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Novel carbon-based microporous nanoplates containing numerous heteroatoms (H-CMNs) are fabricated from regenerated silk fibroin by the carbonization and activation of KOH. The H-CMNs exhibit superior electrochemical performance, displaying a specific capacitance of 264 F/g in aqueous electrolytes, a specific energy of 133 Wh/kg, a specific power of 217 kW/kg, and a stable cycle life over 10000 cycles. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description adma_201204692_sm_suppl.pdf980.3 KB suppl Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 P. Simon, Y. Gogotsi, Nat. Mater. 2008, 7, 845. 2 Y. Zhu, S. Murali, M. D. Stoller, K. J. Ganesh, W. Cai, P. J. Ferreira, A. Pirkle, R. M. Wallace, K. A. Cychosz, M. Thommes, D. Su, E. A. Stach, R. S. Ruoff, Science 2011, 332, 1537. 3 J. R. Miller, P. Simon, Science 2008, 321, 651. 4 Y. Zhang, H. Feng, X. Wu, L. Wang, A. Zhang, T. Xia, H. Dong, X. Li, L. Zhang, Int. J. Hydrogen Energy 2009, 34, 4889. 5 L. L. Zhang, X. S. Zhao, Chem. Soc. Rev. 2009, 38, 2520. 6 J. Chmiola, G. Yushin, Y. Gogotsi, C. Portet, P. Simon, P. L. Taberna, Science 2006, 22, 1760. 7 J. Chmiola, C. Largeot, P. L. Taberna, P. Simon, Y. Gogotsi, Angew. Chem. Int. Ed. 2008, 47, 3392. 8 Z.-S. Wu, D.-W. Wang, W. Ren, J. Zhao, G. Zhou, F. Li, H.-M. Cheng, Adv. Funct.Mater. 2010, 20, 3595. 9 X. Liu, P. G. Pickup, J. Power Sources 2008, 176, 410. 10 S. Chen, J. Zhu, X. Wu, Q. Han, X. Wang, ACS Nano 2010, 4, 2822. 11 X. Xie, L. Gao Carbon 2007, 45, 2365. 12 Q. Wu, Y. Xu, Z. Yao, A. Liu, G. Shi, ACS Nano 2010, 4, 1963. 13 J. Jang, J. Bae, M. Choi, S.-H. Yoon, Carbon 2005, 43, 2730. 14 D. Hulicova-Jurcakova, M. Seredych, G. Q. Lu, T. J. Bandosz, Adv. Funct. Mater. 2009, 19, 438. 15 Y. S. Yun, J. Shim, Y. Tak, H.-J. Jin, RSC Adv. 2012, 2, 4353. 16 L. Zhao, L.-Z. Fan, M.-Q. Zhou, H. Guan, S. Qiao, M. Antonietti, M.-M. Titirici, Adv. Mater. 2010, 22, 5202. 17 H. M. Jeong, J. W. Lee, W. H. Shin, Y. J. Choi, H. J. Shin, J. K. Kang, J. W. Choi, Nano Lett. 2011, 11, 2472. 18 S. Park, Y. Hu, J. O. Hwang, E.-S. Lee, L.B. Casabianca, W. Cai, J. R. Potts, H.-W. Ha, S. Chen, J. Oh, S. O. Kim, Y.-H. Kim, Y. Ishii, R. S. Ruoff, Nat.Commun. 2012, 3, 638. 19 C. Du, N. Pan, Nanotechnology 2006, 17, 5314. 20 K. H. An, W. S. Kim, Y. S. Park, J.-M. Moon, D. J. Bae, S. C. Lim, Y. S. Lee, Y. H. Lee Adv. Funct. Mater. 2001, 11, 387. 21 http://faostat3.fao.org/ 22 A. Motta, L. Fambri, C. Migliaresi, Macromol. Chem. Phys. 2002, 203, 1658. 23 H.-J. Jin, J. Park, V. Karageorgiou, U.-J. Kim, R. Valluzzi, P. Cebe, D. L. Kaplan, Adv. Funct. Mater. 2005, 15, 1241. 24 E. Raymundo-Piñero, K. Kierzek, J. Machnikowski, F. Béguin, Carbon 2006, 44, 2498. 25 E. Frackowiak, F. Béguin, Carbon 2001, 39, 937. 26 Y. Hernandez, V. Nicolosi, M. Lotya, F. M. Blighe, Z. Sun, S. De, I. T. Mcgovern, B. Holland, M. Byrne, Y. K. Gunko, J. J. Boland, P. Niraj, G. Duesberg, S. Krishnamurthy, R. Goodhue, J. Hutchison, V. Scardaci, A. C. Ferrari, J. N. Coleman, Nat. Nanotechnol. 2008, 3, 563. 27 H.-J. Jin, D. L. Kaplan, Nature 2003, 424, 1057. 28 J. E. Bailey, A. J. Clarke, Nature 1971, 234, 529. 29 W. Watt, W. Johnson, Nature 1975, 257, 210. 30 M. A. Lillo-Ródenas, D. Cazorla-Amorós, A. Linares-Solano, Carbon 2006, 41, 267. 31 E. Raymundo-Piñero, P. Azais, T. Cacciaguerra, D. Cazorla-Amorós, A. Linares-Solano, F. Béguin, Carbon 2005, 43, 786. 32 Y. J. Kim, Y. Abe, T. Yanagiura, K. C. Park, M. Shimizu, T. Iwazaki, S. Nakagawa, M. Endo, M. S. Dresselhaus, Carbon 2007, 45, 2116. Citing Literature Volume25, Issue14April 11, 2013Pages 1993-1998 ReferencesRelatedInformation