Preparation and Crystal Structure of the Silver(I) p-Toluenesulfonate−p-Aminobenzoic Acid Complex Polymer Adduct, the First Reported Example of a Silver(I) Complex Involving Two Different Organic Acid Species
期刊:Inorganic Chemistry [American Chemical Society] 日期:1996-01-01卷期号:35 (10): 2711-2712被引量:52
标识
DOI:10.1021/ic950900u
摘要
The silver(I) complex adduct with p-toluenesulfonate and p-aminobenzoic acid, catena-(μ-4-aminobenzoic acid)(μ-4-toluenesulfonato-O,O',O'')silver(I), has been prepared and its structure determined by X-ray diffraction. This compound represents the first structurally characterized example of a complex of silver(I) involving two different organic acid species. The complex network polymer is based on a distorted tetrahedral AgO3N center with silver bonded to oxygens from sulfonate residues of three independent p-toluenesulfonate molecules [Ag−O = 2.309−2.518(3) Å] and the amine nitrogen of a p-aminobenzoic acid adduct molecule [Ag−N = 2.223(3) Å].