自旋(空气动力学)
自旋极化
偶极子
共振(粒子物理)
凝聚态物理
手性(物理)
物理
化学
电偶极矩
联轴节(管道)
核磁共振
原子物理学
材料科学
量子力学
手征异常
电子
热力学
费米子
冶金
Nambu–Jona Lasinio模型
作者
Piotr Garbacz,A. D. Buckingham
摘要
It is predicted that, for two spin-1/2 nuclei coupled by indirect spin-spin coupling in a chiral molecule, chirality-sensitive induced electric polarization can be observed at the frequencies equal to the sum and difference between the spin resonance frequencies. Also, an electric field oscillating at the difference frequency can induce spin coherences which allow the direct discrimination between enantiomers by nuclear magnetic resonance. The dominant contribution to the magnitude of these expected chiral effects is proportional to the permanent electric dipole moment and to the antisymmetric part of the indirect spin-spin coupling tensor of the chiral molecule. Promising compounds for experimental tests of the predictions are derivatives of 1,3-difluorocyclopropene.
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