Uniformly Distributed Mixed Matrix Membranes via a Solution Processable Strategy for Propylene/Propane Separation

Abstract Aggregation of filler particles during the formation of mixed matrix membranes is difficult to avoid when filler loadings exceed a 10–15 wt %. Such agglomeration usually leads to poor membrane performance. In this work, using a ZIF‐67 metal–organic framework (MOF) as filler along with surface modification of Ag 4 tz 4 to improve processability and selective olefin adsorption, we demonstrate that highly loaded with a very low agglomeration degree membranes can be synthesized displaying unmatched separation selectivity (39) for C 3 H 6 /C 3 H 8 mixtures and high permeability rates (99 Barrer), far surpassing previous reports in the literature. Through molecular dynamics simulation, the enhanced compatibility between ZIF‐67 and polymer matrix with adding Ag 4 tz 4 was proven and the tendency in gas permeability and C 3 H 6 selectivity in the mixed matrix membranes (MMMs) were well explained. More importantly, the membrane showed a wide range of pressure and temperature resistance, together with remarkable long‐term stability (>900 h). The modification method might help solve interface issues in MMMs and can be extended to the fabrication of other fillers to achieve high performance MMMs for gas separation.