材料科学
光致发光
壳聚糖
发光
分析化学(期刊)
光子上转换
煅烧
光谱学
傅里叶变换红外光谱
纳米颗粒
纳米复合材料
核化学
纳米技术
化学工程
光电子学
化学
催化作用
生物化学
物理
色谱法
量子力学
工程类
作者
P. Chau,Dang Van Thai,Vu Thi Thai Ha,Dinh Xuan Loc,Tiến Đại Nguyễn,Bui Hong Van,Tran Kim Anh
标识
DOI:10.1149/2162-8777/acae03
摘要
Nanospherical upconversion luminescence particles (UCLPs) Gd 2 O 3 :Er 3+ and Gd 2 O 3 :Er 3+ @ chitosan (CS) were prepared by step-by-step precipitation and calcination of the available nitrate rare Earth sales and chitosan. The morphology and composition of as-prepared samples were characterized by field emission electron spectroscopy (FESEM) and Fourier transform infrared (FT-IR) spectroscopy. The synthesized UCLPs were non-agglomerate spheres in uniform nanoscale. The quantitative amount of chitosan was well coated with the gain surface of the UCLPs Gd 2 O 3 :Er 3+ to obtain Gd 2 O 3 :Er 3+ @CS nanocomposite. The down-conversion luminescent intensity of Gd 2 O 3 :Er 3+ NSP is lower than Gd 2 O 3 :Er 3+ @CS NSP samples, but luminescent characterizations were non-change. The photoluminescence (PL) of the green emission range of all UCLPs samples with chitosan-coated and -uncoated took the leading position. By using a diode laser excitation with 975 nm of wavelength, the detected intensity of red emission is more remarkably detected than green emissions. The two-photon mechanism for both green and red emissions of nanophosphor was observed. As a result, these might be promising opportunities to conjugate with various bio subjects that could be used in medical applications.
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