催化作用
分解
氨
氨生产
化学
化学工程
钌
无机化学
有机化学
工程类
作者
Wenjie Yan,Binglian Liang,Guiyue Bi,Hongying Zhuo,Weijue Wang,Hongmin Duan,Guoliang Xu,Fanan Wang,Yang Su,Tianyu Zhang,Xiaofeng Yang,Yanqiang Huang
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2024-08-29
标识
DOI:10.1021/acssuschemeng.4c03829
摘要
Ru-based catalysts feature an intrinsic activity toward NH3 decomposition, while their catalytic mechanism associated with the interface with support remains elusive. Herein, with the interfacial regulation of Ru catalysts by TiO2 via strong metal–support interactions (SMSI), i.e., Ru/TiO2, an enhanced activity of NH3 decomposition can be realized with a turnover frequency of hydrogen production 2-fold higher than that on Ru/SiO2. With characterizations and density functional theory calculations, the newly generated Ru/TiO2–x interface with the electron-rich Ru sites was proven to not only facilitate the adsorption of ammonia and its N–H bond cleavage but also promote the associative desorption of N* species. Moreover, the poisoning kinetics of hydrogen during reactions can also be alleviated due to the associative desorption of H* occurring primarily on the residual Ru surface. This work demonstrates that interfacial regulation provides an efficient strategy for the catalytic activity modulation of Ru-based catalysts especially in NH3 decomposition.
科研通智能强力驱动
Strongly Powered by AbleSci AI