Self‐Powered Iontronic Capacitive Sensing Unit with High Sensitivity in Charge‐Output Mode

Abstract The operation of iontronic capacitive sensors typically requires an external alternating current (AC) power source, resulting in additional energy consumption and AC‐frequency‐related sensing performance. Here, a class of self‐powered iontronic capacitive sensing units (SICSUs) is proposed based on a dynamic electric double layer (EDL), with a significant charge sensitivity of up to 24270 pC N −1 , surpassing most piezoelectric materials by nearly 10 times. The effects of various design parameters and loading conditions on the sensing performance of the SICSUs are systematically investigated. The EDL at the hydrogel‐electrode interface is characterized in situ, revealing the underlying mechanism for high sensitivity and linearity. The capability of SICSUs in detecting diverse human‐related mechanical loads is demonstrated. Furthermore, a robotic hand equipped with a SICSU‐based artificial algesia sensor is fabricated to mimic the withdrawal reflex behavior of a human hand when its skin detects noxious stimuli caused by sharp objects.