纳米孔
润湿
材料科学
电解质
纳米孔
吸附
纳米技术
多孔性
纳米
化学工程
吸附
接触角
水溶液
渗透(战争)
碳纤维
多孔介质
电极
化学
复合材料
有机化学
物理化学
复合数
工程类
运筹学
作者
Irene Lamata-Bermejo,Waldemar Keil,Karlo Nolkemper,Julian Heske,Janina Kossmann,Hossam Elgabarty,Martin Wortmann,Mirosław Chorążewski,Claudia Schmidt,Thomas D. Kühne,Nieves López‐Salas,Mateusz Odziomek
标识
DOI:10.1002/anie.202411493
摘要
Understanding how water interacts with nanopores of carbonaceous electrodes is crucial for energy storage and conversion applications. A high surface area of carbonaceous materials does not necessarily need to translate to a high electrolyte‐solid interface area. Herein, we study the interaction of water with nanoporous C1N1 materials to explain their very low specific capacity in aqueous electrolytes despite their high surface area. Water was used to probe chemical environments, provided by pores of different sizes, in 1H MAS NMR experiments. We observe that regardless of their high hydrophilicity, only a negligible portion of water can enter the nanopores of C1N1, in contrast to a reference pure carbon material with a similar pore structure. The common paradigm that water easily enters hydrophilic pores does not apply to C1N1 nanopores below a few nanometers. Calorimetric and sorption experiments demonstrated strong water adsorption on the C1N1 surface, which restricts water mobility across the interface and impedes its penetration into the nanopores.
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