外层电子转移
内球面电子转移
协调球
电催化剂
电合成
氧化还原
电子转移
化学
电化学
氨
金属
无机化学
化学物理
光化学
电极
物理化学
离子
有机化学
作者
Akshay Haridas,Ritwik Mondal,Bhojkumar Nayak,Musthafa Ottakam Thotiyl
出处
期刊:Langmuir
[American Chemical Society]
日期:2024-09-03
卷期号:40 (37): 19458-19466
被引量:1
标识
DOI:10.1021/acs.langmuir.4c01836
摘要
Electrochemistry of outer-sphere redox molecules involves an essentially intact primary coordination sphere with minimal secondary sphere adjustments, resulting in very fast electron transfer events even without a noble metal-based electrocatalyst. Departing from conventional electrocatalytic paradigms, we incorporate these minimal reaction coordinate adjustments of outer-sphere species to stimulate the electrocatalysis of energetically challenging inner-sphere substrates. Through this approach, we are able to show an intricate 8e
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