Molecule‐Assisted Chemical Bath Deposition of Tin Oxide Electron Transport Layers in Perovskite Solar Cells

Chemical bath deposition (CBD) is a widely used approach to deposit the tin oxide (SnO 2 ) electron transport layer (ETL) in the perovskite solar cell (PSC). However, the defect states in the CBD‐resulted SnO 2 ETLs limit the electron extraction/transport from the perovskite to the ETL and lead to poor PSC performance. Herein, ethylenediaminetetraacetic acid dipotassium (EDTA‐2K) is used as an additive in the CBD precursor of the SnO 2 ETL, which results in the chelation of Sn 2+ and EDTA during the hydrolysis process. This strategy decreases the concentration of free Sn 2+ in the precursor for hydrolysis and slows down the CBD process, thus attributes to the decreased surface defect states as well as the enhanced conductivity of the ETL. As a result, the EDTA‐2K additive makes the CBD SnO 2 ETL with efficient electron extraction and transporting capability. The champion device achieves a power conversion efficiency (PCE) of 21.87%, which is significantly higher than that of the pristine CBD SnO 2 ‐based device (20.25%). In addition, the device with an active area of 1.21 cm 2 achieves a high PCE of 19.23%. This strategy makes the CBD SnO 2 an excellent ETL candidate for the development of low‐cost and large‐scale PSCs.