氧化还原
蒽醌
流动电池
水溶液
化学
储能
化学工程
材料科学
纳米技术
有机化学
电极
物理化学
功率(物理)
物理
量子力学
工程类
电解质
作者
Kiana Amini,Emily F. Kerr,Thomas Y. George,Abdulrahman Alfaraidi,Yan Jing,Tatsuhiro Tsukamoto,Roy G. Gordon,Michael J. Aziz
出处
期刊:Meeting abstracts
日期:2023-08-28
卷期号:MA2023-01 (27): 1751-1751
标识
DOI:10.1149/ma2023-01271751mtgabs
摘要
Redox flow batteries (RFBs) are large-scale energy storage technologies that are attractive due to their safety, flexible design, and long life. Among different types of RFBs, aqueous organic systems have gained a lot of attention due to the possibility of tailoring the redox properties by modifying the organic chemical structure. We introduce 2-2-propionate ether anthraquinone (abbreviated 2-2PEAQ), which is a singly substituted anthraquinone that is synthesized via a facile synthetic route from potentially inexpensive precursors. 2-2PEAQ has the lowest molecular weight (MW = 296.07 g/mol) among the anthraquinone derivatives reported to date that can deliver an extremely low capacity fade rate (<0.02%/day), low membrane permeability (<1 x 10 -13 cm 2 /s), high solubility (≥1 M transferrable electrons) and acceptable redox potential (OCV >~1.0 V vs. Fe(CN) 6 3-/4- ) for use in aqueous organic flow batteries. Having a smaller MW per mole transferrable electrons in species that can be synthesized via simple synthesis routes is highly preferable because both attributes correlate with low mass production cost. We will discuss the degradation mechanisms of 2-2PEAQ and report its performance in the negolyte of a redox flow battery under practically relevant conditions, advancing the prospects for commercialization of grid-scale aqueous organic redox flow batteries.
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