Fluorinated Graphene–Lewis-Base Polymer Composites as a Multifunctional Passivation Layer for High-Performance Perovskite Solar Cells

钝化 材料科学 钙钛矿(结构) 能量转换效率 石墨烯 图层(电子) 掺杂剂 复合材料 相对湿度 聚合物 光电子学 化学工程 纳米技术 兴奋剂 热力学 物理 工程类
作者
Qiang Lou,Hailing Guo,Jiahao Chen,Yuzheng Guo,Xiaomeng Zhu,Tong Chen,Xinxin Xu,Jingyi Xu,Zhengjie Xu,Hang Zhou
出处
期刊:ACS Applied Materials & Interfaces [American Chemical Society]
卷期号:15 (33): 39374-39383 被引量:11
标识
DOI:10.1021/acsami.3c07893
摘要

Increasing the open-circuit voltage (Voc) stands as a critical strategy for further improving the efficiency of organic–inorganic halide perovskite solar cells (PSCs). Lewis basic polymers, such as polymethyl methacrylate (PMMA), are considered as an effective approach to reduce the nonradiative recombination at the perovskite surface and protect the photoactive layer against moisture. However, the insulating nature of PMMA inherently leads to increased series resistance in PSCs. Here, we propose a multifunctional passivation layer (FG–PMMA) composed of fluorinated graphene (FG) and PMMA, offering high conductivity, a good passivation effect, and excellent hole transportation capabilities. The introduction of FG not only reduces the resistance of the PMMA layer but also improves its hydrophobicity. More importantly, we found that fluoride, which acts as a p-type dopant in graphene, can further reduce the nonradiative recombination centers by forming PbF2 with uncoordinated Pb0 at the perovskite/hole transport layer interface. As a result, the introduction of FG–PMMA significantly enhances the photovoltaic performance, with a record-high open-circuit voltage (Voc) of 1.247 V and an average power conversion efficiency of 22.91%, higher than those of PMMA-based devices (20.75%, 1.210 V), as well as increasing the device's moisture stability, with over 90% of the initial efficiency maintained after 1200 h of aging at room temperature and a relative humidity of 35%.
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