超级电容器
微型多孔材料
电容
材料科学
电极
碳纳米纤维
碳纤维
木质素
纳米技术
化学工程
复合材料
碳纳米管
化学
工程类
复合数
有机化学
物理化学
作者
Chang Ma,Ge Song,Zhengyi Li,Hongbin Wu,Chunju Wang,Yue Wang,Xiangwu Zhang,Yan Song,Jingli Shi
标识
DOI:10.1016/j.est.2024.111465
摘要
Self-supporting three-dimensional fiber network derived from electrospinning technology is an ideal structure for constructing high-loading thick electrodes. In this work, microporous carbon nanofiber membranes (MCNMs) are prepared by electrospinning using lignin as precursor and TEOS as additive. The introduction of TEOS plays a crucial role in producing abundant micropores and improving the thermal stability of fibers. With the aid of TEOS, the obtained lignin-based MCNMs present a high specific surface area of 1197 m2 g−1, microporosity of 84.1 % and notably-enhanced diameter retention rate. With excellent flexibility and satisfactory strength, the lignin-based MCNMs exhibit an impressive specific capacitance of 282 F g−1 at 0.2 A g−1 when used as a self-supporting electrode for supercapacitors. By layer-by-layer stacking of the lignin-based MCNMs, thick electrode is constructed and presents an areal capacitance of 5.72 F cm−2 at mass-loading of 25.4 mg cm−2. Further, the supercapacitor assembled by thick electrodes exhibits an areal power density of 0.54 mW cm−2 and energy density of 0.08 mWh cm−2 at low rate, and 54 mW cm−2 and 0.03 mWh cm−2 at high rate. With merits of renewable raw materials, unsophisticated process, and prominent performance, the lignin-based MCNMs provide a promising alternative electrode material for supercapacitors.
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