Effects of graphene content in alkaline silicate electrolyte on AA1060 pure aluminum micro‐arc oxidation coating

材料科学 石墨烯 电解质 涂层 硅酸盐 微弧氧化 化学工程 冶金 无机化学 电极 复合材料 纳米技术 微观结构 化学 物理化学 工程类 镁合金
作者
D.H. Li,Xin Jing,Han Chen,Kun Sun,Wei Chen,Hua‐gui Huang,Weijie Ren
出处
期刊:International Journal of Applied Ceramic Technology [Wiley]
卷期号:21 (3): 1789-1801 被引量:1
标识
DOI:10.1111/ijac.14717
摘要

Abstract Ceramic coatings were obtained by micro‐arc oxidation (MAO) on the surface of AA1060 pure aluminum in alkaline silicate electrolyte with the addition of graphene. The effects of graphene contents in the range of 0–.30 g/L in the electrolyte on surface morphology, corrosion resistance, and wear resistance of the ceramic coatings were investigated. The outer surface structure, outer surface element content, coating cross‐section structure, coating cross‐section element content, coating/substrate interface structure, and coating phase were characterized by scanning electron microscope and X‐ray diffraction. Potentiodynamic polarization and electrochemical impedance spectroscopy were used to evaluate the corrosion behavior of MAO samples in a 3.5‐wt% NaCl solution. In addition, the resistance to sliding and abrasive wear of the oxide coating were studied experimentally. The results show that the alkaline silicate electrolyte with the addition of graphene has a significant effect on the characteristics of MAO coating. The performance of micro‐arc oxide coatings is best when the graphene content in the electrolyte is .15 g/L, the average thickness of the film is 7.24 μm, the average pore size is 6.07 μm, the impedance value is approximately 4.01 × 106 Ω, and its friction coefficient is .55.

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