The Effect of Sodium Dodecyl Sulphate Additives on the Electrochemical Performance of Aqueous Zinc Ion Batteries

Aqueous zinc ion batteries are considered one of the most promising energy storage devices due to their high safety, low cost, and ease of fabrication. However, the growth of anode dendrites and continuous side reactions during cycling limit the practical application of zinc ion batteries. In this paper, sodium dodecyl sulfate (SDS) was used as an aqueous electrolyte additive to improve the surface deposition of Zn²⁺. The experimental results show that the SDS electrolyte additive forms a protective layer on the anode surface through electrostatic action and inhibits the growth of dendritic protruding dendrites by increasing the zinc deposition overpotential, as well as by limiting the two-dimensional diffusion of Zn²⁺ on the negative electrode surface of the aqueous zinc ion battery. As a result, adding SDS improves the discharge specific capacity of NVP/Zn batteries at high voltages and results in improved capacity retention. The cycling stability of NVP/Zn batteries was greatly enhanced by using a battery containing 1% SDS that still had a discharge specific capacity of 71 mAh/g after 100 cycles at a charging current density of 1 C, with a capacity retention rate of 89%. This work provides a simple and feasible solution to the anode problem of aqueous zinc ion batteries.