Fabrication and assembly of supercapacitors based on Ni-based MOF and their derivative materials for enhancing electrochemical performances

Metal-organic frameworks (MOFs) are a class of porous materials that have been gradually applied in the field of supercapacitors, but they still present major challenges due to their inherent instability and poor conductivity. Herein, in order to solve these problems, Ni-based MOFs and their derivative materials with a particular spherical structure were prepared using a special calcination method. This unique structure not only improves the conductivity of the electrode, but also promotes the transport of electrons and ions during the electrochemical energy storage process. The as-prepared Ni-MOF@M-a4 has an amazing specific capacitance (637.78 F g