Fe-ZIF-derived hollow porous carbon nanofibers for electromagnetic wave absorption

The nanomaterials with multiple components and various heterogeneous interfaces have been considered as preferred efficient electromagnetic wave (EMW) absorbers. In this paper, Fe atoms were bonded to a zeolitic imidazole framework (Fe-ZIF) and Fe-ZIF-derived hollow porous carbon nanofibers (Fe-HPCNFs) were prepared by the microfluid electrospinning method. The EMW absorption properties of carbon nanofibers (CNFs), Fe-ZIF-derived carbon nanofibers (Fe-CNFs), and Fe-ZIF-derived hollow porous carbon nanofibers (Fe-HPCNFs) were systematically studied. The results showed that Fe-HPCNFs has the best performance, when the thickness was only 2.0 mm, the Fe-HPCNFs achieved a minimum RL loss of −46.9 dB at 17.38 GHz, with an effective absorption bandwidth of 3 GHz. The Fe-HPCNF is a flexible, ultralightweight, self-supported material as a potential high-efficiency EMW absorber.