Rational Design of MXene Hollow Fiber Membranes for Gas Separations

One scalable and facile dip-coating approach was utilized to construct a thin CO₂-selection layer of Pebax/PEGDA-MXene on a hollow fiber PVDF substrate. An interlayer spacing of 3.59 Å was rationally designed and precisely controlled for the MXene stacks in the coated layer, allowing efficient separation of the CO₂ (3.3 Å) from N₂ (3.6 Å) and CH₄ (3.8 Å). In addition, CO₂-philic nanodomains in the separation layer were constructed by grafting PEGDA into MXene interlayers, which enhanced the CO₂ affinity through the MXene interlayers, while non-CO₂-philic nanodomains could promote CO₂ transport due to the low resistance. The membrane could exhibit optimal separation performance with a CO₂ permeance of 765.5 GPU, a CO₂/N₂ selectivity of 54.5, and a CO₂/CH₄ selectivity of 66.2, overcoming the 2008 Robeson upper bounds limitation. Overall, this facile approach endows a precise controlled molecular sieving MXene membrane for superior CO₂ separation, which could be applied for interlayer spacing control of other 2D materials during membrane construction.