Selective Hydrodeoxygenation of Lignin‐Derived Phenolic Monomers and Dimers to Cycloalkanes on Pd/C and HZSM‐5 Catalysts

加氢脱氧 催化作用 木质素 芳基 单体 酚类 化学 有机化学 烷基 选择性 高分子化学 聚合物
作者
Chen Zhao,Johannes A. Lercher
出处
期刊:Chemcatchem [Wiley]
卷期号:4 (1): 64-68 被引量:306
标识
DOI:10.1002/cctc.201100273
摘要

ChemCatChemVolume 4, Issue 1 p. 64-68 Communication Selective Hydrodeoxygenation of Lignin-Derived Phenolic Monomers and Dimers to Cycloalkanes on Pd/C and HZSM-5 Catalysts Dr. Chen Zhao, Dr. Chen Zhao Catalysis Research Center and Department of Chemistry, Technische Universität München, Garching 85747 (Germany), Fax: (+49) 89-28913544Search for more papers by this authorProf. Dr. Johannes A. Lercher, Corresponding Author Prof. Dr. Johannes A. Lercher [email protected] Catalysis Research Center and Department of Chemistry, Technische Universität München, Garching 85747 (Germany), Fax: (+49) 89-28913544Catalysis Research Center and Department of Chemistry, Technische Universität München, Garching 85747 (Germany), Fax: (+49) 89-28913544Search for more papers by this author Dr. Chen Zhao, Dr. Chen Zhao Catalysis Research Center and Department of Chemistry, Technische Universität München, Garching 85747 (Germany), Fax: (+49) 89-28913544Search for more papers by this authorProf. Dr. Johannes A. Lercher, Corresponding Author Prof. Dr. Johannes A. Lercher [email protected] Catalysis Research Center and Department of Chemistry, Technische Universität München, Garching 85747 (Germany), Fax: (+49) 89-28913544Catalysis Research Center and Department of Chemistry, Technische Universität München, Garching 85747 (Germany), Fax: (+49) 89-28913544Search for more papers by this author First published: 14 November 2011 https://doi.org/10.1002/cctc.201100273Citations: 263Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Suffocating phenols: A catalyst system consisting of Pd/C and HZSM-5 shows an extremely high selectivity in removing oxygen-containing groups (hydroxyl, methoxy, ketone, alkylOaryl, and arylOaryl) in lignin-derived substituted phenolic monomers and dimers through a metal-acid catalyzed cascade cleavage of CO bonds in phenolic dimers and the integrated hydrogenation and dehydration reactions in water at 473 K. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description cctc_201100273_sm_miscellaneous_information.pdf340.8 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume4, Issue1January 2, 2012Pages 64-68 RelatedInformation
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