材料科学
钙钛矿(结构)
平面的
钙钛矿太阳能电池
光电子学
建模与仿真
制作
图层(电子)
能量转换效率
计算机科学
光学
介孔材料
光伏系统
太阳能电池
纳米技术
物理
化学
模拟
电气工程
医学
结晶学
替代医学
生物化学
催化作用
病理
工程类
计算机图形学(图像)
出处
期刊:Applied Optics
[The Optical Society]
日期:2019-09-03
卷期号:58 (26): 7006-7006
摘要
The metal-halide perovskite solar cell (PSC) has risen to the forefront of photovoltaic research, and presents the potential for low-cost fabrication with high-power conversion efficiency. Better understanding of the PSC operation mechanism is necessary and required to further improve the performance of the device. Therefore, in addition to numerous experimental studies, some number of optoelectrical simulations are necessary. However, usually, simulations are either electrical or optical and more in relation to one-dimensional (1D) structures such as planar cells. In this study, an approach to optoelectrical simulation of a 3D solar cell, such as the mesoporous PSC, has been presented. First, the 3D layers, such as the mesoporous layer, are modeled to a 1D effective layer using Bergman's effective medium theory. By using the spectral density function, this effective medium theory is able to introduce the 1D equivalent of the 3D layer. Then, the optical results by transfer matrix method are transferred to the SCAPS-1D code, in order to simulate the EQE spectrum and the JV curve of solar cells. The simulation results were compared with the experimental results for two mesoporous PSC, one without a capping perovskite layer and the other with the capping layer. The results of this study showed that the proposed procedure can simulate and therefore investigate the optoelectrical properties of 3D mesoporous solar cells, which can also be extended to similar 3D structures. This 1D simulation procedure, compared to 3D simulation, has a much lower execution time offering more simplicity and no need for commercial codes or specific hardware.
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