Copper-catalysed synthesis of α-alkylidene cyclic carbonates from propargylic alcohols and CO2
铜
化学
催化作用
有机化学
作者
Alejandro Cervantes‐Reyes,Kaveh Farshadfar,Matthias Rudolph,Frank Röminger,Thomas Schaub,Alireza Ariafard,A. Stephen K. Hashmi
出处
期刊：Green Chemistry [The Royal Society of Chemistry] 日期：2020-12-21卷期号：23 (2): 889-897被引量：35
标识
DOI：10.1039/d0gc03990j
摘要
A sterically encumbered, nine-membered NHC-copper(i) complex was shown to be an effective catalyst for the chemical fixation of CO2 by propargylic alcohols for the diastereoselective synthesis of α-alkylidene cyclic carbonates.
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