阿特拉津
氧化还原
辐照
降级(电信)
分解
光催化
光化学
化学
可见光谱
核化学
无机化学
催化作用
材料科学
杀虫剂
生态学
生物
有机化学
光电子学
物理
核物理学
电信
计算机科学
作者
Yanbiao Shi,Xiaobing Wang,Xiufan Liu,Cancan Ling,Wenjuan Shen,Lizhi Zhang
标识
DOI:10.1016/j.apcatb.2020.119229
摘要
We demonstrate that visible light irradiation can promote Fe3S4 Fenton oxidation of atrazine. The visible light irradiation could increase the atrazine Fenton degradation rate by 4.9 times. The enhanced atrazine degradation activity under visible light was attributed to the higher surficial Fe(II)/Fe(III) ratio of Fe3S4 and the efficient surface iron redox cycle triggered by visible light. Experimental results revealed that the operando formation of FeOOH on the Fe3S4 surface blocked the iron redox cycle and inhibited the H2O2 decomposition, accounting for the largely decreased Fenton activity of Fe3S4 in dark, while these problems were successfully solved by the introduction of visible light irradiation, which excite Fe3S4 to produce abundant photo-generated electrons and O2− for efficient regeneration of active Fe(II) species of Fe3S4 and in-situ formed FeOOH.
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