丁烷
催化作用
马来酸酐
选择性
结晶度
化学
焦磷酸盐
氧化还原
烷烃
无机化学
有机化学
结晶学
聚合物
酶
共聚物
作者
Bin He,Linlin Nan,Zihang Li,Bo Wen,Jingyang Niu,Ruixia Liu
标识
DOI:10.1002/slct.201803263
摘要
Abstract Vanadyl pyrophosphate contained catalysts (VPP) are of great importance for the selective oxidation of light alkane to chemicals. Achieving high conversion of alkane with a high selectivity of target products is critical for the practical applications of VPP. Here we selected three Mo species H 5 Mo 12 O 41 P (PMA), MoO 3 , and (NH 4 ) 6 Mo 7 O 4 ⋅4H 2 O (HAM) as promoters for VPP catalysts. Performance evaluation shows that all Mo‐promoted VPP catalysts have much better catalytic performance than those without Mo promoter, which are mainly attributed to the different Mo species could induce the formation of active crystal and affect the redox characteristic to varying degrees. Moreover, SEM revealed that the PMA possess a “shape memory” function, which result in crystallinity of (200) in PMA‐VPO is higher than others. H 2 ‐TPR suggested that PMA could increase the amount of oxygen and reduce the reduction activation energy, which is beneficial to enhance the activity of VPP. The presented results may be helpful for selecting superior metal promoter and facilitated the process of VPP catalyst development for n ‐butane selective oxidation.
科研通智能强力驱动
Strongly Powered by AbleSci AI