Robust, buoyant, superhydrophobic PVB/SiO2 coatings were successfully formed on wood surface through a one-step solvothermal method and a nanoimprint lithography method. The as-prepared PVB/SiO2/wood specimens were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR), thermogravimetric/differential thermogravimetric (TG-DTG) analyses. The superhydrophobic property and abrasion resistance of rose-petal-like wood were measured and assessed by water contact angle (WCA) and sand abrasion tests. The results show that PVB/SiO2/wood not only exhibited a robust superhydrophobic performance with a WCA of 160° but also had excellent durability and thermostability during the sand abrasion tests and against corrosive liquids. Additionally, the as-prepared PVB/SiO2/wood specimens show high buoyancy.