环丁二烯
化学
钴
环戊二烯基络合物
循环伏安法
电化学
极谱法
金属
过渡金属
配体(生物化学)
无机化学
分子
有机化学
物理化学
催化作用
电极
生物化学
受体
标识
DOI:10.1016/s0020-1693(00)89300-7
摘要
Electrochemical oxidation of cobalt sandwich complexes CoCpL, where Cp is η5-cyclopentadienyl and L an η4-diolefine or cyclobutadiene ligand, was investigated by means of cyclic voltammetry and polarography. Oxidation is reversible or nearly so for compounds where L is a cyclic diolefine (I–III) or a cyclobutadiene (VI) and for the methylated complexesCo(C5Me5)(C5Me5R) (R = Me, Ph) (VII) and irreversible for CoCp(C5H5Ph) (IV) and the complexes V where L is a divinylborane.
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