摘要
Polymer Engineering & ScienceVolume 54, Issue 1 p. 1-16 Review Electrically conductive multiphase polymer blend carbon-based composites Paul J. Brigandi, Corresponding Author Paul J. Brigandi The Dow Chemical Company, 727 Norristown Road, Spring House, Pennsylvania 19477-0904 Center for Polymer Science and Engineering, Lehigh University, Bethlehem, Pennsylvania 18015-3195The Dow Chemical Company, 727 Norristown Road, Spring House, Pennsylvania 19477-0904. E-mail: [email protected]Search for more papers by this authorJeffrey M. Cogen, Jeffrey M. Cogen The Dow Chemical Company, 727 Norristown Road, Spring House, Pennsylvania 19477-0904Search for more papers by this authorRaymond A. Pearson, Raymond A. Pearson Center for Polymer Science and Engineering, Lehigh University, Bethlehem, Pennsylvania 18015-3195Search for more papers by this author Paul J. Brigandi, Corresponding Author Paul J. Brigandi The Dow Chemical Company, 727 Norristown Road, Spring House, Pennsylvania 19477-0904 Center for Polymer Science and Engineering, Lehigh University, Bethlehem, Pennsylvania 18015-3195The Dow Chemical Company, 727 Norristown Road, Spring House, Pennsylvania 19477-0904. E-mail: [email protected]Search for more papers by this authorJeffrey M. Cogen, Jeffrey M. Cogen The Dow Chemical Company, 727 Norristown Road, Spring House, Pennsylvania 19477-0904Search for more papers by this authorRaymond A. Pearson, Raymond A. Pearson Center for Polymer Science and Engineering, Lehigh University, Bethlehem, Pennsylvania 18015-3195Search for more papers by this author First published: 26 March 2013 https://doi.org/10.1002/pen.23530Citations: 108Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract The present review focuses on summarizing key advances made on controlling polymer blend morphology to improve electrical conductivity in carbon-based polymer composite materials, including those based on carbon black, carbon nanotubes, and graphene. Fundamentals for controlling polymer morphology and the distribution of conductive fillers in various polymer composite systems and the impact on the electrical, rheological, mechanical, and thermal properties are reviewed. The concept of triple percolation and its beneficial effect on electrical conductivity is then reviewed. A high level overview of key theories and mechanisms related to phase morphology, percolation, and conductive properties in polymer composites is provided. POLYM. ENG. SCI., 54:1–16, 2014. © 2013 Society of Plastics Engineers REFERENCES 1R. Strumpler and J. Glatz-Reichenbach, J. 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