Recent theoretical and experimental advancements in the application of van Oss–Chaudury–Good acid–base theory to the analysis of polymer surfaces I. General aspects

Abstract The acid-base theory as developed by van Oss, Chaudury and Good is a powerful tool to analyze the surface free energy of polymeric materials; however, some problems are encountered in its application and some authors have shown that these problems can be theoretically solved considering this theory as an example of the so-called LFER theories. From this point of view, the definition of a well-defined scale of acid-base strength and the use of a wide and well-equilibrated, appropriate set of liquids is very important. In the present paper some recent results are presented which are based on the mathematical approach discussed by Della Volpe and Siboni in previous papers. The treatment is developed as a list of questions, Frequently Asked Questions (FAQs), whose theoretical implications are discussed using numerical examples chosen from the literature. Some literature data, collected by the opponents of the acid-base theory and recently published, are re-analysed using these methods, showing that they constitute a well-defined set to calculate, with a good precision, the acidbase components of the considered materials and the interfacial energies of liquids used. The present paper is the premise of a second one, in which a set of contact angles data collected by the authors and by other researchers will be analysed following the principles discussed here. Keywords: ACID-BASE THEORYCONTACT ANGLESURFACE FREE ENERGYCONDITION NUMBER