Efficient Protection of Silver Nanowire Transparent Electrodes by All-Biorenewable Layer-by-Layer Assembled Thin Films

An efficient protection strategy for silver nanowire-based transparent electrodes (AgNW TEs) is developed to enhance their poor adhesion force on substrates and thermal, optical, chemical, and electrical stabilities. Chitin nanofibers (CNFs) and alkali lignin (AL), which possess high mechanical property, a gas/moisture barrier, and UV absorption properties, are successively assembled on AgNW TEs through layer-by-layer (LBL) assembly based on their oppositely charged surfaces. The formation of LBL-assembled CNFs and AL (CNF/AL)10 bilayers, where 10 is the optimized number of bilayers, on the aldehyde-modified AgNW (Al-AgNW) TEs does not deteriorate their electrical conductivity (17.3 ± 2.1 Ω/□) and transmittance (90.1 ± 0.3% at 550 nm), and the (CNF/AL)10 bilayer-coated Al-AgNW [(CNF/AL)10@Al-AgNW] TEs present considerable enhancement in their adhesion force and thermal, optical, chemical, and electrical durability. In detail, their optoelectrical properties are stable over 200 cycles of the scotch peel-off test, for 10 h sonication, up to 350 °C, under UV/O3 treatment for 100 min, in 10% HCl and 28% NH3 for 6 and 12 h, and at an electrical potential up to 14 V, respectively. These features make (CNF/AL)10@Al-AgNW TEs suitable as a durable high-performance transparent heater.