还原胺化
胺化
动力学分辨率
化学
催化作用
支化(高分子化学)
有机化学
组合化学
对映选择合成
作者
Vijay N. Wakchaure,Jian Zhou,S.D. Hoffmann,Benjamin List
标识
DOI:10.1002/anie.201001715
摘要
Branching out: An organocatalytic reductive amination of α-branched ketones using dynamic kinetic resolution is reported. The cis-2-substituted cyclohexyl amines were obtained in high diastereoselectivity and enantioselectivity from the corresponding ketones. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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