Comparison of the UV/chlorine and UV/H2O2 processes in the degradation of PPCPs in simulated drinking water and wastewater: Kinetics, radical mechanism and energy requirements

化学 废水 流出物 药品和个人护理产品的环境影响 高级氧化法 环境化学 激进的 降级(电信) 反应速率常数 饮用水净化 水处理 紫外线 过氧化氢 污水处理 动力学 环境工程 有机化学 环境科学 材料科学 物理 电信 量子力学 光电子学 计算机科学
作者
Kaiheng Guo,Zihao Wu,Shuwen Yan,Bo Yao,Weihua Song,Zhechao Hua,Xuewen Zhang,Xiujuan Kong,Xuchun Li,Jingyun Fang
出处
期刊:Water Research [Elsevier BV]
卷期号:147: 184-194 被引量:263
标识
DOI:10.1016/j.watres.2018.08.048
摘要

The degradation of pharmaceuticals and personal care products (PPCPs) by the UV/H2O2 and UV/chlorine processes was compared at practical concentrations in simulated drinking water and wastewater. In pure water, the UV/chlorine process performed better than the UV/H2O2 process for the degradation of 16 PPCPs among the investigated 28 PPCPs under neutral conditions. Interestingly, the UV/chlorine approach was superior to the UV/H2O2 approach for the removal of all PPCPs in simulated drinking water and wastewater at the same molar oxidant dosage. The radical sink by oxidants and/or H2O was 2–3 orders of magnitude higher in UV/chlorine than UV/H2O2 in pure water. Thus, the UV/chlorine process was less affected by the water and wastewater matrices than UV/H2O2. In UV/chlorine, the concentration of ClO• was calculated to be ∼3 orders of magnitude greater than that of HO• in pure water, and the reactivities of ClO• with some PPCPs were as high as > 108 M−1 s−1. ClO• was mainly scavenged by the effluent organic matter (EfOM) with a rate constant of 1.8 × 104 (mg L−1)−1 s−1 in wastewater. Meanwhile, secondary radicals such as Br•, Br2•-, ClBr•- and CO3•- further contributed to PPCP degradation by the UV/chlorine process in wastewater, whose concentrations were at least 2 orders of magnitude higher than that in UV/H2O2. Compared with the UV/H2O2 process, the UV/chlorine process saved 3.5–93.5% and 19.1%–98.1% electrical energy per order (EE/O) for PPCP degradation in simulated drinking water and wastewater, respectively.
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