石墨氮化碳
降级(电信)
催化作用
纳米复合材料
材料科学
碳纤维
荧光
氮化碳
化学
光化学
纳米颗粒
核化学
化学工程
纳米技术
无机化学
光催化
有机化学
复合数
电信
复合材料
工程类
量子力学
物理
计算机科学
作者
Qiulan Li,Dezhi Yang,Qinhong Yin,Wanyi Li,Yaling Yang
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2022-01-27
卷期号:5 (2): 1925-1934
被引量:27
标识
DOI:10.1021/acsanm.1c03551
摘要
The heterogeneous Cu-based solid catalysts have attracted enormous attention of researchers in different potential applications. In this work, a graphitic carbon nitride/copper-doped carbon dots (g-C3N4/Cu-CDs) nanocomposite with both intrinsic peroxidase- and oxidase-like (POD- and OXD-like) activities was successfully prepared. Due to the synergistic catalytic enhancement and electron transmission provided by g-C3N4, both POD- and OXD-like activities of g-C3N4/Cu-CDs were significantly improved compared with those of g-C3N4 and Cu-CDs. Moreover, upon the addition of H2O2, g-C3N4/Cu-CDs could catalyze the oxidation of colorless o-phenylenediamine (OPD) to form a yellow fluorescent product 2,3-diaminophenazine (DAP) with yellow fluorescence. Interestingly, the OPD + H2O2 + g-C3N4/Cu-CDs system could be inhibited by phenolic compounds, which could efficiently decrease the DAP fluorescence. Based on this, a method for the quantitative detection of total phenolic substances was established. Meanwhile, the use of OXD-like activity of nanocomposites was extended for the degradation of phenols (e.g., 2-CP), which showed a good degradation efficiency. Based on the result that the conversion of Cu+/Cu2+/Cu0 plays pivotal roles in promoting the generation of radicals (i.e., •OH and •O2–), a possible catalytic mechanism of g-C3N4/Cu-CDs was deduced. These findings showed that the proposed g-C3N4/Cu-CDs exhibit great potential to become a green catalyst for the degradation of phenolic pollutants in the environment.
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