材料科学
反射损耗
复合数
微波食品加热
阻抗匹配
吸收(声学)
三元运算
光电子学
碳化
异质结
金属有机骨架
纳米技术
电阻抗
复合材料
计算机科学
化学
电信
电气工程
有机化学
吸附
工程类
扫描电子显微镜
程序设计语言
作者
Fei Wu,Lingyun Wan,Qingyan Li,Qiuyu Zhang,Baoliang Zhang
标识
DOI:10.1016/j.compositesb.2022.109839
摘要
In recent years, metal-organic framework (MOF)-derived absorbers have attracted much attention in the field of microwave absorption. It is interesting and difficult to construct multiple MOF-on-MOF heterostructures. Herein, we combine two unique anisotropic epitaxial growth strategies to build binary assemblies [email protected] (DM) and [email protected] (DMC), and then the ternary assembly [email protected]@MIL-88C (DMM). The formation mechanisms of the assembled structure are clarified. Besides, they are converted into magnetic porous carbon-based absorbers (DM-700 and DMM-700) through a facile carbonization process. The microwave absorption mechanisms are elucidated. The results indicate that the exquisite multi-element composite structure endows the absorber with suitable impedance matching characteristics, complementary loss mechanisms and excellent electromagnetic loss capabilities. It is worth noting that DM-700 exhibits a remarkable minimum reflection loss (RLmin) of −67.5 dB under a matching thickness of 3.6 mm, corresponding to an effective absorption bandwidth (EAB, RL < −10 dB) of 2.0 GHz and the filler loading of 55%. The optimized absorber DMM-700 successfully achieves the optimization of the above-mentioned microwave absorbing properties. While maintaining the desirable RLmin (−56.4 dB), the matching thickness is reduced (2.4 mm), and at the same time, EAB is doubled (4.0 GHz). This study might provide a new idea for the construction of sophisticated absorbers with multi-MOF-on-MOF structures.
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