A Different Reaction Pathway for the Reduction of Aromatic Nitro Compounds on Gold Catalysts

Angewandte ChemieVolume 119, Issue 38 p. 7404-7407 Zuschrift A Different Reaction Pathway for the Reduction of Aromatic Nitro Compounds on Gold Catalysts† Avelino Corma Prof., Avelino Corma Prof. [email protected] Instituto de Tecnología Química (UPV-CSIC), Av. de los Naranjos s/n, Valencia, Spain, Fax: (+34) 963-877-809Search for more papers by this authorPatricia Concepción Dr., Patricia Concepción Dr. Instituto de Tecnología Química (UPV-CSIC), Av. de los Naranjos s/n, Valencia, Spain, Fax: (+34) 963-877-809Search for more papers by this authorPedro Serna, Pedro Serna Instituto de Tecnología Química (UPV-CSIC), Av. de los Naranjos s/n, Valencia, Spain, Fax: (+34) 963-877-809Search for more papers by this author Avelino Corma Prof., Avelino Corma Prof. [email protected] Instituto de Tecnología Química (UPV-CSIC), Av. de los Naranjos s/n, Valencia, Spain, Fax: (+34) 963-877-809Search for more papers by this authorPatricia Concepción Dr., Patricia Concepción Dr. Instituto de Tecnología Química (UPV-CSIC), Av. de los Naranjos s/n, Valencia, Spain, Fax: (+34) 963-877-809Search for more papers by this authorPedro Serna, Pedro Serna Instituto de Tecnología Química (UPV-CSIC), Av. de los Naranjos s/n, Valencia, Spain, Fax: (+34) 963-877-809Search for more papers by this author First published: 17 September 2007 https://doi.org/10.1002/ange.200700823Citations: 129 † We thank the Spanish government (project MAT 2006-14274-C02-01 and grant FPU AP2003-4635) for financial support. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Ein Au/TiO2-Katalysator vermeidet die Bildung von Kondensationsprodukten bei der Hydrierung aromatischer Nitroverbindungen. Anhand von kinetischen Untersuchungen und In-situ-IR-Messungen, die belegen, dass nur geringe Mengen an Nitrosobenzol erzeugt werden und dass das Hydroxylamin und Nitrosobenzol stark mit der Katalysatoroberfläche wechselwirken, wurde eine neuartige Reaktionssequenz postuliert (siehe Bild). Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z700823_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1F. Visentin, G. Puxty, O. M. Kut, K. Hungerbuehler, Ind. Eng. Chem. Res. 2006, 45, 4544. 10.1021/ie0509591 CASWeb of Science®Google Scholar 2M. P. Nemtseva, O. V. Lefedova, M. A. Zuenko, L. A. Antina, Zh. Fiz. Khim. 2004, 78, 1571. CASGoogle Scholar 3M. Studer, S. Neto, H.-U. Blaser, Top. Catal. 2000, 13, 205. 10.1023/A:1009050804228 CASWeb of Science®Google Scholar 4P. Baumeister, H.-U. Blaser, M. Studer, Catalysis Letters 1998 (volume date 1997), 49, 219. 10.1023/A:1019034128024 Web of Science®Google Scholar 5G. Neri, M. G. Musolino, L. Bonaccorsi, A. Donato, L. Mercadante, S. Galvagno, Ind. Eng. Chem. Res. 1997, 36, 3619. 10.1021/ie950505b CASWeb of Science®Google Scholar 6I. A. Makaryan, V. I. Savchenko, Stud. Surf. Sci. Catal. 1993, 75, 2439. 10.1016/S0167-2991(08)64319-0 CASWeb of Science®Google Scholar 7 7aR. F. Kovar, F. E. Armond (U.S. Air Force), U.S. Patent 3,975,444, 1976; Google Scholar 7bM. Suchy, P. Winternitz, M. Zeller (Ciba-Geigy), WO Patent 91/02278, 1991; Google Scholar 7cA. Burawoy, J. P. Critchley, Tetrahedron 1959, 5, 340. 10.1016/0040-4020(59)80025-9 CASWeb of Science®Google Scholar 8R. A. Sheldon, CHEMTECH 1994, 24, 38. CASWeb of Science®Google Scholar 9U. Siegrist, P. Baumeister, H.-U. Blaser, Chem. Ind. 1998, 75, 207–219. CASWeb of Science®Google Scholar 10A. Corma, P. Serna, Science 2006, 313, 332. 10.1126/science.1128383 CASPubMedWeb of Science®Google Scholar 11H.-U. Blaser, Science 2006, 313, 312. 10.1126/science.1131574 CASPubMedWeb of Science®Google Scholar 12F. Haber, Z. Elektrochem. 1898, 22, 506. Google Scholar 13E. A. Gelder, S. D. Jackson, C. M. Lok, Chem. Commun. 2005, 522. 10.1039/b411603h CASPubMedWeb of Science®Google Scholar Citing Literature Volume119, Issue38September 24, 2007Pages 7404-7407 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. ReferencesRelatedInformation