过硫酸盐
苯甲酸
化学
矿化(土壤科学)
动力学
辐照
核化学
硫酸盐
羟基自由基
激进的
腐植酸
化学计量学
降级(电信)
无机化学
催化作用
有机化学
电信
肥料
物理
量子力学
计算机科学
核物理学
氮气
作者
Valencia Elvira Sugihartono,Nicolaus N.N. Mahasti,Yu-Jen Shih,Yen‐Chieh Huang
出处
期刊:Chemosphere
[Elsevier]
日期:2022-06-01
卷期号:296: 133663-133663
被引量:7
标识
DOI:10.1016/j.chemosphere.2022.133663
摘要
The strong oxidant, persulfate (PS, S2O82-), was applied to treat the synthetic wastewater of benzoic acid (BA) under UV irradiation. UVC light initiated a chain reaction that derived the sulfate radical (SO4•-) and hydroxyl radical (HO•) from S2O82- ion. The experiment parameters, including light irradiation (UVA and UVC), pH, dose ratio ([PS]0/[BA]0), initial concentration ([BA]0, mg/L), was optimized based on degradation efficiency and total organic carbon (TOC) removal of BA, which reached up to 100% and 96%, respectively, under pH 3.0. The best dose ratio was close to equivalent stoichiometry (and [PS]0/[BA]0 = 15) for the treatment of 100 mg-BA/L, suggesting that UV/S2O82- was able to completely convert BA to carbon dioxide and water. The scavenging test showed that SO4•- contributed to about 60% of degradation rate, which the HO• predominated the mineralization rate, i.e., TOC removal. A consecutive kinetic model was proposed to clarify the reaction sequence and rate-determining factor of photo-persulfate oxidation for benzoic acid.
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