材料科学
氧化物
空隙(复合材料)
金属
电介质
化学气相沉积
铝
复合材料
原子层沉积
图层(电子)
冶金
纳米技术
光电子学
作者
Soo Geun Lee,Heok-Sang Oh,Sun-Rae Kim,Seung-Heon Song,Sun Hu Park,U‐In Chung,Geung Won Kang
标识
DOI:10.1109/iitc.1999.787105
摘要
In 0.25 /spl mu/m design-rule devices, notch-shaped micro-voids were observed in metal lines where high density plasma (HDP) chemical vapor deposition (CVD) oxide was used as an inter-metal dielectric (IMD) material. In this study, we have investigated the process conditions related to the metal voiding. When the HDP CVD oxide deposition temperature decreased, the void formations were reduced but still occurred at narrower metal lines with 0.64 and 0.75 /spl mu/m pitches. In the case where TiN was used instead of Ti in the glue layer and Al capping layer, metal voids were not observed. This result suggests that the tensile stress induced by the reaction between Ti and Al at high temperature during HDP CVD oxide deposition is the major driving force for metal void formation. At high temperature, easy diffusion accelerates the formation of metal voids. Heat treatment at 450/spl deg/C for 30 min after metal patterning, which produces the Ti-Al reaction before deposition of the HDP CVD oxide, is proposed as the metal void prevention method.
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