Organic Covalent Interaction‐based Frameworks as Emerging Catalysts for Environment and Energy Applications: Current Scenario and Opportunities

纳米技术 灵活性(工程) 共价键 材料科学 催化作用 多孔性 共价有机骨架 化学 有机化学 统计 数学 复合材料
作者
Tahir Rasheed,Adeel Ahmad Hassan,Tauqir Ahmad,Sardaraz Khan,Farooq Sher
出处
期刊:Chemistry-an Asian Journal [Wiley]
卷期号:18 (13) 被引量:15
标识
DOI:10.1002/asia.202300196
摘要

Abstract The term “covalent organic framework” (COF) refers to a class of porous organic polymeric materials made from organic building blocks that have been covalently bonded. The preplanned and predetermined bonding of the monomer linkers allow them to demonstrate directional flexibility in two‐ or three‐dimensional spaces. COFs are modern materials, and the discovery of new synthesis and linking techniques has made it possible to prepare them with a variety of favorable features and use them in a range of applications. Additionally, they can be post‐synthetically altered or transformed into other materials of particular interest to produce compounds with enhanced chemical and physical properties. Because of its tunability in different chemical and physical states, post‐synthetic modifications, high stability, functionality, high porosity and ordered geometry, COFs are regarded as one of the most promising materials for catalysis and environmental applications. This study highlights the basic advancements in establishing the stable COFs structures and various post‐synthetic modification approaches. Further, the photocatalytic applications, such as organic transformations, degradation of emerging pollutants and removal of heavy metals, production of hydrogen and Conversion of carbon dioxide (CO 2 ) to useful products have also been presented. Finally, the future research directions and probable outcomes have also been summarized, by focusing their promises for specialists in a variety of research fields.
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