阳极
电解质
材料科学
锂(药物)
储能
阴极
自行车
有机自由基电池
相间
化学工程
多硫化物
无机化学
纳米技术
电极
化学
考古
遗传学
量子力学
生物
功率(物理)
物理化学
内分泌学
工程类
物理
历史
医学
作者
Zheng Li,Yuan Li,Chen‐Xi Bi,Qiankui Zhang,Li‐Peng Hou,Xi‐Yao Li,Jin Ma,Qiang Zhang,Bo‐Quan Li,Rui Wen,Qiang Zhang
标识
DOI:10.1002/adfm.202304541
摘要
Abstract Lithium–sulfur (Li–S) batteries promise great potential as high‐energy‐density energy storage devices. However, the parasitic reactions between lithium polysulfides (LiPSs) and Li metal anodes render limited cycling lifespan of Li–S batteries. Herein, an organic‐rich solid electrolyte interphase (SEI) is constructed to inhibit the LiPS parasitic reactions and achieve long‐cycling Li–S batteries. Concretely, 1,3,5‐trioxane is introduced as a reactive co‐solvent that decomposes on Li anode surfaces and contributes organic components to the SEI. The as‐constructed organic‐rich SEI effectively inhibits the LiPS parasitic reactions and protects working Li metal anodes. Consequently, the cycling lifespan of Li–S coin cells with 50 µm Li anodes and 4.0 mg cm −2 sulfur cathodes is prolonged from 130 to 300 cycles by the organic‐rich SEI. Furthermore, the organic‐rich SEI enables a 3.0 Ah‐level Li–S pouch cell to achieve a high energy density of 400 Wh kg −1 and stable 26 cycles. This study affords an effective organic‐rich SEI to inhibit the LiPS parasitic reactions and inspires rational SEI design to achieve long‐cycling Li–S batteries.
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