过电位
析氧
纳米复合材料
材料科学
塔菲尔方程
分解水
化学工程
氧化物
锰
电解水
催化作用
电化学
电极
纳米技术
电解
冶金
化学
生物化学
物理化学
光催化
电解质
工程类
作者
Zainab M. Almarhoon,Karam Jabbour,Sumaira Manzoor,Syed Imran Abbas Shah,Muhammad Faheem Ashiq,Muhammad Yousaf Ur Rehman,Muhammad Fahad Ehsan,Muhammad Najam‐ul‐Haq,Muhammad Naeem Ashiq
出处
期刊:Fuel
[Elsevier]
日期:2024-05-01
卷期号:363: 130919-130919
被引量:1
标识
DOI:10.1016/j.fuel.2024.130919
摘要
Individuals experiencing poverty and possessing limited financial resources are particularly susceptible to impacts of climate change and rising costs associated with fossil fuels. In response to this pressing issue, researchers are actively investigating water oxidation as a sustainable solution to mitigate the challenges posed by climate changes and energy crisis. The oxygen evolution reaction (OER), which plays a pivotal role in water electrolysis, necessitates the utilization of highly stable and efficient electrode materials to overcome its intrinsic sluggish kinetics and enhance the overall efficiency of the electrochemical device. This investigation employed a reduction method to synthesize manganese oxide (MnO) nanoparticles, using manganese telluride (MnTe) as the base material, yielding a MnTe@MnO nanocomposite. This innovative composite was subsequently immobilized onto a nickel foam (NF) substrate. Remarkably, the MnTe@MnO nanocomposite exhibited exceptional OER performance in a 1.0 M alkaline solution, manifesting an impressively low overpotential of 208 mV at a benchmark current density of 10 mA cm−2. This overpotential significantly surpassed that of the individual MnTe and MnO electrode materials, underscoring the synergistic advantages of the MnTe@MnO nanocomposite. Further analysis revealed a notably shallow Tafel slope of 39 mV dec-1, indicative of the enhanced reaction kinetics and electrocatalytic efficiency inherent to the MnTe@MnO nanocomposite. Moreover, the durability assessment over a span of 30 h demonstrated minimal current loss, emphasizing the substantial electrocatalytic active surface area of the fabricated nanocomposite.
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