Review of Transition Metal Chalcogenides and Halides as Electrode Materials for Thermal Batteries and Secondary Energy Storage Systems

Transition metal chalcogenides and halides (TMCs and TMHs) have been extensively used and reported as electrode materials in diverse primary and secondary batteries. This review summarizes the suitability of TMCs and TMHs as electrode materials focusing on thermal batteries (utilized for defense applications) and energy storage systems like mono- and multivalent rechargeable batteries. The report also identifies the specific physicochemical properties that need to be achieved for the same materials to be employed as cathode materials in thermal batteries and anode materials in monovalent rechargeable systems. For example, thermal stability of the materials plays a crucial role in delivering the performance of the thermal battery system, whereas the electrical conductivity and layered structure of similar materials play a vital role in enhancing the electrochemical performance of the mono- and multivalent rechargeable batteries. It can be summarized that nonlayered CoS2, FeS2, NiS2, and WS2 were found to be ideal as cathode materials for thermal batteries primarily due to their better thermal stability, whereas the layered structures of these materials with a coating of carbon allotrope (CNT, graphene, rGO) were found to be suitable as anode materials for monovalent alkali metal ion rechargeable batteries. On the other hand, vanadium, titanium, molybdenum, tin, and antimony based chalcogenides were found to be suitable as cathode materials for multivalent rechargeable batteries due to the high oxidation state of cathode materials which resists the stronger field produced during the interaction of di- and trivalent ions with the cathode material facilitating higher energy density with minimal structural and volume changes at a high rate of discharge.