超级电容器
尖晶石
制作
材料科学
能量密度
电极
冶金
纳米技术
工程物理
电容
化学
工程类
医学
替代医学
物理化学
病理
作者
Zahra Batool,Atiq ur Rehman,Ahmad Mukhtar,Muhammad Waqas Iqbal,Saikh Mohammad Wabaidur,Masoom Raza Siddiqui,Jeffrey T. Glass
标识
DOI:10.1016/j.est.2023.110092
摘要
Three spinel ferrites, AgFe2O4, CoFe2O4, and ZnFe2O4, were successfully synthesized using the hydrothermal technique and were employed as electrode materials for supercapacitor applications. These spinel ferrites underwent a comprehensive assessment of their crystallinity, morphology, and electrochemical performance. The structural analysis using X-ray diffraction convincingly demonstrated the excellent crystallization of these compounds, indicating the development of single-phase spinel ferrites. A uniform cubic structure was successfully achieved. TEM analysis revealed that the as-synthesized nanomaterials exhibited a spherical shape with particle sizes ranging from 50 to 100 nm. In terms of electrochemical performance, utilizing a three-electrode configuration, the cubic spinel CoFe2O4 nanoparticles, synthesized at 200 °C, exhibited outstanding results, with a maximum specific capacitance of 2146.40 F/g at 3 mV/s, surpassing the performance of AgFe2O4 and ZnFe2O4. To create a hybrid asymmetric device utilizing all three spinel ferrites, activated carbon served as the negative electrode, while AgFe2O4, CoFe2O4, and ZnFe2O4 were employed as positive electrodes. Notably, the CoFe2O4 electrode outperformed the others, achieving a remarkable 94 % coulombic efficiency and demonstrating long-term cyclic stability with 87 % capacitance retention after 10,000 cycles. The findings of this study underscore the significant potential of the synthesized nanoparticles as promising candidates for hybrid supercapacitors and various other electrochemical applications.
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