化学
亚胺离子
激进的
转化(遗传学)
烷基
有机化学
组合化学
离子
光化学
药物化学
生物化学
基因
作者
Zakhar M. Rubanov,Vitalij V. Levin,Alexander D. Dilman
出处
期刊:Organic Letters
[American Chemical Society]
日期:2023-11-28
卷期号:25 (48): 8751-8755
被引量:3
标识
DOI:10.1021/acs.orglett.3c03764
摘要
A method for the conversion of aldehydes to ketones via the preliminary formation of aldiminines is described. The imines are involved in acid promoted Minisci-type reaction with alkyl radicals generated from esters of N-hydroxylphthalimide under photoredox conditions. Aminyl radical cations formed after the addition of the iminium ions are believed to be key intermediates, which determine the reaction outcome.
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