材料科学
润滑油
润滑
色散(光学)
分散稳定性
摩擦学
金属
化学工程
水溶液中的金属离子
氧化物
复合材料
纳米技术
冶金
纳米颗粒
工程类
物理
光学
作者
Hongxiang Yu,Xiaolong Liu,Wei-Sheng Meng,Zhiwen Zheng,Dan Qiao,Dapeng Feng,Zhenbin Gong,Guojun Dong
标识
DOI:10.1016/j.matdes.2022.111251
摘要
• Three kinds of ultrathin two-dimension metal-organic framework (2D-MOF) nanosheets with different metal ions (Ni 2+ , Zn 2+ , and Cu 2+ ) were successfully synthesized. • Ni-MOF nanosheets as a new lubricating oil additive exhibit the best dispersion stability, and the relative absorbance is as high as 0.85 after five days. • The addition of 0.1 wt% Ni-MOF nanosheets obtains the best tribological properties, reducing friction by 33.2 ± 12.4 % and wear by 98.7 ± 0.14 % compared with pure base oil. • The excellent lubrication performance of Ni-MOF nanosheets originates from their interlayer sliding effect, polishing effect, and formation of tribofilm with concrete structure, and demonstrates their potential for industrial use. Two-dimension (2D) nano materials are diffusely employed as lubricant additives. In this paper, three kinds of ultrathin 2D metal-organic framework (MOF) nanosheets with different metal ions (Ni 2+ , Zn 2+ , and Cu 2+ ) were successfully synthesized by ultrasonic assisted self-assembly under appropriate solvent ratio. Ni-MOF nanosheets as a new additive in 500 N system exhibit the best dispersion stability and lubrication performance, which is related to its maximum absolute value of Zeta potential. Compared with pure 500 N, the best tribological properties were obtained with the addition of 0.1 wt% Ni-MOF nanosheets, reducing friction by 33.2 ± 12.4 % and wear by 98.7 ± 0.14 %. The excellent performance originates from interlayer sliding effect, polishing effect, and tribofilm with concrete structure. The iron oxide particles embedded in the tribofilm play a supporting structrue for the whole tribofilm. The carbonaceous and nitrogenous compounds are filled around the iron oxide particles, which makes tribofilm denser and more smooth. The further friction tests under higher sliding velocity and longer term reveal the potential industrial use of Ni-MOF nanosheets.
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