电解质
钝化
锂(药物)
X射线光电子能谱
阳极
电极
介电谱
电化学
材料科学
化学工程
碳酸锂
金属
表面改性
无机化学
化学
分析化学(期刊)
纳米技术
离子
冶金
图层(电子)
离子键合
物理化学
有机化学
内分泌学
工程类
医学
色谱法
作者
Josu Seara,Francisco Alcaide,V.L. Barrio,Anass Benayad,Elixabete Ayerbe
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2022-08-01
卷期号:169 (8): 080526-080526
被引量:1
标识
DOI:10.1149/1945-7111/ac8a1d
摘要
Lithium metal electrodes have been submitted to a long-term storage in contact with carbonated-based electrolyte at different temperatures, with the aim of gaining more understanding on the impact of aging conditions on the lithium metal surface. To do so, the evolution of lithium surface∣electrolyte interface has been monitored via electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy and FE-SEM techniques, to correlate the change of the interface properties with the chemical and morphological modifications at the electrode’s surface. After this aging, lithium electrodes were galvanostatically cycled in symmetric Li∣Li coin cell configuration at 10, 25 and 45 °C. Through this approach, a better cycling stability was observed in those cells stored at 45 °C, which can be ascribed to the more compact lithium electrodeposition than that observed in the rest of cells previously aged at lower temperatures. These results indicate that calendar at high temperature condition benefits lithium electrode performance, which can be attributed to a homogeneous passivation of the metal surface with fluorine and/or phosphate-based compounds, following XPS measurements, which can improve the behaviour of the solid electrolyte interface.
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