双氰胺
离子液体
化学
三元运算
热力学
表面张力
粘度
大气温度范围
三元数制
大气压力
水溶液
有机化学
物理
计算机科学
程序设计语言
催化作用
海洋学
地质学
相(物质)
作者
E. Quijada-Maldonado,S. van der Boogaart,J.H. Lijbers,G.W. Meindersma,André B. de Haan
标识
DOI:10.1016/j.jct.2012.02.027
摘要
In this paper, experimental densities and dynamic viscosities of 1-ethyl-3-methylimidazolium based ionic liquids (ILs) with the anions acetate and dicyanamide are presented in a wide temperature range (298.15 to 343.15 K) at atmospheric pressure. Surface tension of these ILs was measured at T = 298.15 K. The effect of water and/or ethanol compositions on densities and dynamic viscosities of these ILs are studied in binary and ternary mixtures. A quadratic mixing rule was used to correlate binary and ternary liquid densities. The Eyring–Patel–Teja model, which is recommended for polar and aqueous systems, is used to correlate dynamic viscosity data over the whole range of compositions and temperatures in binary and ternary mixtures. Temperature-dependent interaction parameters are introduced here to account for the changes of viscosities with temperature showing good agreements with experimental data.
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