拉曼光谱
甘氨酸
太赫兹辐射
太赫兹光谱与技术
光谱学
谱线
材料科学
相干反斯托克斯拉曼光谱
分子物理学
化学
核磁共振
物理
光学
光电子学
拉曼散射
量子力学
氨基酸
生物化学
标识
DOI:10.1088/0022-3727/38/19/024
摘要
Terahertz time-domain spectroscopy is used to investigate the absorption and dispersion of polycrystalline α- and γ-glycine in the spectral region 0.5–3.0 THz. The spectra exhibit distinct features in these two crystalline phases. The observed far-infrared responses are attributed to intermolecular vibrational modes mediated by hydrogen bonds. We also measure the Raman spectra of the polycrystalline and dissolved glycine in the frequency range 28–3900 cm−1. The results show that all the vibrational modes below 200 cm−1 are nonlocalized but are of a collective (phonon-like) nature. Furthermore, the temperature dependence of the Raman spectra of α-glycine agrees with the anharmonicity mechanism of the vibrational potentials.
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