超级电容器
原材料
电容
废物管理
碳纤维
储能
比表面积
化学工程
多孔性
电化学
活性炭
纳米技术
电极
材料科学
工程类
化学
有机化学
复合材料
物理
催化作用
吸附
物理化学
功率(物理)
复合数
量子力学
作者
T. Ratnaji,L. John Kennedy
标识
DOI:10.1016/j.diamond.2020.108100
摘要
It is still a difficulty to develop supercapacitor electrodes at a reasonable cost. The present work reports on the preparation of hierarchical porous carbon from tea wastes for supercapacitors application. Herein, the study finds a fruitful route for tea waste management wherein conversion of waste to worth resources is adopted. Waste tea leaves served as a raw material for the preparation of hierarchical porous carbons by two stage, process (precarbonization and chemical activation) aiming to produce a high performance supercapacitors electrode material. The samples were chemically activated using KOH in the temperature range, 600 °C to 900 °C after precarbonization. The BET surface area of the carbon samples were between 16 m2 g−1 to 1029 m2 g−1. The pore drilling and pore winding effect led to considerable development of well-defined micro-meso porosity. In particular, the hierarchical porous carbon prepared at 800 °C (WTC8) exhibited a superior performance for supercapacitor with highest capacitance of 490 F/g and over 99.7% capacitance retentivity even after 1000 cycles at 8 A/g. The outstanding electrochemical performance shows that hierarchical porous carbon electrodes derived from used tea solid waste behaves as a promising candidate for high performance supercapacitors and also proposes the proof of concept of waste to worth.
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