Carbonized cellulose microsphere@void@MXene composite films with egg-box structure for electromagnetic interference shielding

Well established internal multilayered structures have been demonstrated to contribute greatly towards outstanding shielding effectiveness (SE) in electromagnetic interference (EMI) shielding systems. A specific encapsulation by intercalating carbonized cellulose microspheres into Ti3C2Tx MXene layers ([email protected]) is elaborately designed. The [email protected]@MXene composite films with “egg-box” structure are ultimately achieved by annealing treatment with spherical [email protected] as “egg” and Ti3C2Tx MXene layers as “box”. The unique structure with interior void space is attributed to internal multiple reflections of incident electromagnetic waves (EMW) and contributes to the enhancement of EMW absorption. Thanks to the electrically conductive network of Ti3C2Tx MXene adhering to cellulose microspheres surface, the egg-box structure composite films exhibit superb electrical conductivity of 1672.0 ± 7.1 S cm−1 and excellent specific EMI shielding efficiency (up to 18637.14 dB cm2 g−1) at an ultrathin thickness (12.1 ± 0.8 μm). This hierarchical porous egg-box structure offers an ideal potential for application in highly efficient EMI shielding systems.