Cobalt(II)-Based 3D Coordination Polymer with Unusual 4,4,4-Connected Topology as a Dual-Responsive Fluorescent Chemosensor for Acetylacetone and Cr2O72–

A cobalt(II) coordination polymer with an unusual 4,4,4-connected network was hydrothermally synthesized and observed with high thermal, solvent, and pH stabilities. This polymer can serve as the first dual-responsive fluorescent chemosensor for the selective detection of acetylacetone and Cr2O72- ion (pH 3.0) in aqueous systems.