初湿浸渍
催化作用
傅里叶变换红外光谱
催化燃烧
甲苯
化学
程序升温还原
化学工程
兴奋剂
红外光谱学
燃烧
材料科学
无机化学
选择性
核化学
物理化学
有机化学
工程类
光电子学
作者
Yongqiang Wang,Xiao Li,Chaocheng Zhao,Fang Liu,Li Shi
摘要
Pd/La 0.8 Ce 0.2 MnO 3 catalysts supported on various kinds of zeolites (ZSM‐5, MOR, NaY, and β) were prepared by incipient wetness impregnation method, and these catalysts were investigated by Brunauer‐Emmett‐Teller, X‐ray diffraction analysis (XRD), Fourier transform infrared spectroscopy, and H 2 ‐temperature programmed reduction. The catalytic activity of these catalysts was tested for toluene catalytic combustion, and the support effect was investigated. It was found that the ZSM‐5 is the best support than other zeolites (MOR, NaY, and β), because it processes the higher acidity and reducibility, although its specific surface area is smaller than the others. Result of XRD indicates that Pd species are highly dispersed on the surface of the catalysts, and the doping of Pd could greatly improve the activity of La 0.8 Ce 0.2 MnO 3 , the light‐off and complete conversion temperature of Pd/La 0.8 Ce 0.2 MnO 3 /ZSM‐5 are only 112 and 227°C, respectively. © 2017 American Institute of Chemical Engineers Environ Prog, 37: 215–220, 2018
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